Abstract
Cadmium sulfide quantum dots were synthesized and deposited on glass substrates
by chemical bath deposition (CBD) technique using cadmium sulfate and thiourea
solutions in the presence of a 4,4’-(1,2-ethanediyldinitrilo)bis-(2-pentanone)
(EDDBP) tetradentate ligand as a complexing agent. The order of reagents addition
was varied to deposit films that were characterized for their surface morphological,
optical, structural, and solid-state properties using a scanning electron microscope
(SEM), a UV-visible spectrophotometer, an X-ray diffractometer (XRD), and
Brunauer-Emmet-Teller (BET) analyses. The optimal condition for film deposition
using the normal sequence of reagents addition was found at pH 8-12 and 298-353 ±
1K and gave films of 2.40-321.06 nm thickness, while the variation in the order of
reagents addition gave improvements in the film properties. The optical properties and
the observed direct band gaps (1.75-3.16 eV) of the films suggest usage in
electroluminescent and solar cell devices since they have a first-order transition. The
XRD patterns of the quantum dots indicated hexagonal wurzite structures, while the
BET confirmed their mesoporous and nanonature.
by chemical bath deposition (CBD) technique using cadmium sulfate and thiourea
solutions in the presence of a 4,4’-(1,2-ethanediyldinitrilo)bis-(2-pentanone)
(EDDBP) tetradentate ligand as a complexing agent. The order of reagents addition
was varied to deposit films that were characterized for their surface morphological,
optical, structural, and solid-state properties using a scanning electron microscope
(SEM), a UV-visible spectrophotometer, an X-ray diffractometer (XRD), and
Brunauer-Emmet-Teller (BET) analyses. The optimal condition for film deposition
using the normal sequence of reagents addition was found at pH 8-12 and 298-353 ±
1K and gave films of 2.40-321.06 nm thickness, while the variation in the order of
reagents addition gave improvements in the film properties. The optical properties and
the observed direct band gaps (1.75-3.16 eV) of the films suggest usage in
electroluminescent and solar cell devices since they have a first-order transition. The
XRD patterns of the quantum dots indicated hexagonal wurzite structures, while the
BET confirmed their mesoporous and nanonature.
Keywords
CdS quantum dot
Electro-luminescent device
Order of reagents addition.
Solar cells
Tetradentate-Schiffbase