Abstract
The grafted vinyl acetate copolymerization lying on chitosan in weak acidic aqueous solution
was examined via using K2S2O8 as initiator. FTIR spectra, DSC, DTG and TGA were used for graft
polymer characterizing. The monomer to chitosan ratio was tested and the optimal grafting
conditions were affixed. the highest grafting percentage PG of production polymers have been
applied to remove Cd(II) ions from water samples through adsorption experiments at pH=7. The
amounts of adsorbed metal ion on the polymers was estimated using atomic absorption
spectrophotometer. The temperature effect on Cd(II) adsorption was studied too. Langmuir and
Freundlich isotherms as well as kinetic study equations were employed to fit the experimental data.
The results of the adsorption equilibrium for Cd(II) fitted well to Langmuir isotherm and the
removal percentage at 30°C after 5 min is 76.65 % and the thermodynamic parameters for the
adsorption are ΔH= 96.87 kJ/mol ΔS= 339.19 J/mol K and ΔG= -5.11, -11.13 and -11.78 kJ/mol in
different temperatures. The kinetic study of these adsorption isotherms showed that all these
isotherms correlates well with the second order equation.
was examined via using K2S2O8 as initiator. FTIR spectra, DSC, DTG and TGA were used for graft
polymer characterizing. The monomer to chitosan ratio was tested and the optimal grafting
conditions were affixed. the highest grafting percentage PG of production polymers have been
applied to remove Cd(II) ions from water samples through adsorption experiments at pH=7. The
amounts of adsorbed metal ion on the polymers was estimated using atomic absorption
spectrophotometer. The temperature effect on Cd(II) adsorption was studied too. Langmuir and
Freundlich isotherms as well as kinetic study equations were employed to fit the experimental data.
The results of the adsorption equilibrium for Cd(II) fitted well to Langmuir isotherm and the
removal percentage at 30°C after 5 min is 76.65 % and the thermodynamic parameters for the
adsorption are ΔH= 96.87 kJ/mol ΔS= 339.19 J/mol K and ΔG= -5.11, -11.13 and -11.78 kJ/mol in
different temperatures. The kinetic study of these adsorption isotherms showed that all these
isotherms correlates well with the second order equation.
Keywords
Adsorption
chitosan
graft copolymerization
kinetics
water treatment.