Abstract
Polymer electrolytes were prepared using the solution cast technology. Under
some conditions, the electrolyte content of polymers was analyzed in constant
percent of PVA/PVP (50:50), ethylene carbonate (EC), and propylene carbonate
(PC) (1:1) with different proportions of potassium iodide (KI) (10, 20, 30, 40, 50
wt%) and iodine (I2) = 10 wt% of salt. Fourier Transmission Infrared (FTIR)
studies confirmed the complex formation of polymer blends. Electrical
conductivity was calculated with an impedance analyzer in the frequency range 50
Hz–1MHz and in the temperature range 293–343 K. The highest electrical
conductivity value of 5.3 × 10-3 (S/cm) was observed for electrolytes with 50 wt%
KI concentration at room temperature. The magnitude of electrical conductivity
was increased with the increase in the salt concentration and temperature. The
blend electrolytes have a high dielectric constant at lower frequencies which may
be attributed to the dipoles providing sufficient time to get aligned with the electric
field, resulting in higher polarization. The reduction of activation energy (Ea)
suggests that faster-conducting electrolyte ions want less energy to move.
some conditions, the electrolyte content of polymers was analyzed in constant
percent of PVA/PVP (50:50), ethylene carbonate (EC), and propylene carbonate
(PC) (1:1) with different proportions of potassium iodide (KI) (10, 20, 30, 40, 50
wt%) and iodine (I2) = 10 wt% of salt. Fourier Transmission Infrared (FTIR)
studies confirmed the complex formation of polymer blends. Electrical
conductivity was calculated with an impedance analyzer in the frequency range 50
Hz–1MHz and in the temperature range 293–343 K. The highest electrical
conductivity value of 5.3 × 10-3 (S/cm) was observed for electrolytes with 50 wt%
KI concentration at room temperature. The magnitude of electrical conductivity
was increased with the increase in the salt concentration and temperature. The
blend electrolytes have a high dielectric constant at lower frequencies which may
be attributed to the dipoles providing sufficient time to get aligned with the electric
field, resulting in higher polarization. The reduction of activation energy (Ea)
suggests that faster-conducting electrolyte ions want less energy to move.
Keywords
Conductivity
Dielectric
electrolytes
FTIR.
impedance