Abstract
Bismuth metal react with dibenzothiazole disulfide (C7H4NS2)2 in
refluxing toluene to give the compound Bi(S2C7H4N)3 through oxidative
addition reaction, similary, a mixture of bismuth, (C7H4NS2)2 and iodine
in 1:1:0.5 molar ratio in refluxing toluene lead to the formation of
Bi(S2C7H4N)2I. Adducts of new bismuth compounds with triphenylphosphine and 1,10-phenanthroline have been synthesized by direct
reaction between the bismuth compounds and the neutral ligand.
Trinuclear complexes of the general formula[Bi(S2C7H4N)3(MCl2)2] were
prepared by a direct reaction of CoCl2.6H2O, NiCl2.6H2O or CuCl2.4H2O
with bismuth compound. The bismuth compounds their adducts and the
complexes have been characterized physico-chemically and spectroscopically.
refluxing toluene to give the compound Bi(S2C7H4N)3 through oxidative
addition reaction, similary, a mixture of bismuth, (C7H4NS2)2 and iodine
in 1:1:0.5 molar ratio in refluxing toluene lead to the formation of
Bi(S2C7H4N)2I. Adducts of new bismuth compounds with triphenylphosphine and 1,10-phenanthroline have been synthesized by direct
reaction between the bismuth compounds and the neutral ligand.
Trinuclear complexes of the general formula[Bi(S2C7H4N)3(MCl2)2] were
prepared by a direct reaction of CoCl2.6H2O, NiCl2.6H2O or CuCl2.4H2O
with bismuth compound. The bismuth compounds their adducts and the
complexes have been characterized physico-chemically and spectroscopically.