Abstract
In this study, thin films of cadmium oxide (CdO) were synthesized using the chemical thermal decomposition method. The films were deposited onto a glass substrate measuring 2.5 cm x 2.5 cm x 1 mm at a temperature of 400°C and a pressure of 2 bars. A total of 20 spray applications were performed, with each spray lasting approximately 10 seconds, and a 180-second interval between sprays. A dedicated chemical decomposition system was established to facilitate the preparation of thin film materials for this research. Subsequently, the prepared films were subjected to ultraviolet (UV) light irradiation for a total of five hours, with each irradiation session lasting one hour. Absorbance and transmittance spectra were recorded after each hour of irradiation across a wavelength range of 350-950 nm using a UV-VIS Double Beam Spectrophotometer. The results indicated that absorbance varied with wavelength, showing a decrease in the absorbance spectrum as irradiation time increased, reaching its minimum at the end of the fifth hour. Conversely, transmittance exhibited a direct increase with longer irradiation durations. Additionally, it was observed that the energy gap decreases with increasing irradiation time, ranging from 2.511 eV to 2.458 eV over the 0 to 5-hour period, with measurements taken at one-hour intervals. The analysis of certain optical constants revealed a decline in the absorption coefficient, extinction coefficient and refractive index as irradiation time increased.
Keywords
Spray pyrolysis technology cadmium oxide optical constants irradiation