Abstract
The combination of quantum materials into electrochemical systems provides a novel
procedure in advanced energy storage technology. This study focused on the use of magic
angle twisted bilayer graphene (MATBG); a material known for its unconventional
superconductivity and superfluid stiffness scaling at cryogenic temperatures suitable for
enhancing battery interfaces under room temperature conditions. By exploiting the
quantum capacitance of MATBG and incorporating it in an adapted Poisson-Nernst-Planck
(PNP) theoretical framework, this study achieved substantial and remarkable
improvements in interfacial energetics and charge-transfer kinetics. Explicitly, the modified
PNP model showed a 50% reduction in interfacial potential gradients (from 8.2×10³ mol/m⁴
to 2.7×10³ mol/m⁴) and a 60% decrease in charge-transfer resistance (Rct), as confirmed by
Nyquist plot analysis. Experimentally, MATBG-integrated battery cells display a threefold
increase in exchange current density (j0) compared to normal or conventional cells, along
with a substantial reduction in voltage hysteresis (0.07 V vs. 0.22 V in control systems)
during cycling. These improvements are linked to the unique electronic characteristic of
MATBG, which facilitates efficient redistribution of charges and eradicates kinetic problems
at the electrode-electrolyte interface. These findings highlight and present the potential of
MATBG as a high-performance quantum-electrochemical interface, which enables high-rate
battery operation with improved energy stability and efficiency. This work bridges quantum
material physics with practical electrochemistry and also opens a novel technique for
designing next-generation energy storage systems that leverage quantum-engineered
interfaces.
procedure in advanced energy storage technology. This study focused on the use of magic
angle twisted bilayer graphene (MATBG); a material known for its unconventional
superconductivity and superfluid stiffness scaling at cryogenic temperatures suitable for
enhancing battery interfaces under room temperature conditions. By exploiting the
quantum capacitance of MATBG and incorporating it in an adapted Poisson-Nernst-Planck
(PNP) theoretical framework, this study achieved substantial and remarkable
improvements in interfacial energetics and charge-transfer kinetics. Explicitly, the modified
PNP model showed a 50% reduction in interfacial potential gradients (from 8.2×10³ mol/m⁴
to 2.7×10³ mol/m⁴) and a 60% decrease in charge-transfer resistance (Rct), as confirmed by
Nyquist plot analysis. Experimentally, MATBG-integrated battery cells display a threefold
increase in exchange current density (j0) compared to normal or conventional cells, along
with a substantial reduction in voltage hysteresis (0.07 V vs. 0.22 V in control systems)
during cycling. These improvements are linked to the unique electronic characteristic of
MATBG, which facilitates efficient redistribution of charges and eradicates kinetic problems
at the electrode-electrolyte interface. These findings highlight and present the potential of
MATBG as a high-performance quantum-electrochemical interface, which enables high-rate
battery operation with improved energy stability and efficiency. This work bridges quantum
material physics with practical electrochemistry and also opens a novel technique for
designing next-generation energy storage systems that leverage quantum-engineered
interfaces.
Keywords
Battery interfaces
Magic-angle graphene
MATBG
Poisson-Nernst-Planck model.
Quantum capacitance
Superfluid stiffness