Abstract
This study investigated the potential of calcined clays from Nigerian deposits in
the production of ternary blends of cement. Clay samples were obtained from three different
locations namely: Ikpeshi, Okpilla and Uzebba. The raw clay samples were then calcined at
700°C and 800°C. Chemical and mineralogical compositions were determined for the raw
and calcined clay samples using XRF and XRD respectively. The chemical composition
confirmed these clays as potential pozzolans with SiO2, Al2O3, and Fe2O3 collectively
exceeding 70%. XRD analysis identified kaolinite and quartz as major mineral phases in the
raw clays, which transformed into metakaolin upon calcination. Compressive strength tests
on mortar samples prepared with 50% substitution of Portland cement with the calcined
clay and limestone, showed that Ikpeshi clay at 800°C had the best strength performance,
with a strength activity index of 0.92 at 28 days, demonstrating superior pozzolanic
potential. Strength development was more significant between 7 and 28 days, indicating the
pozzolanic reaction's contribution to long-term strength. However, the initial strength at 3
days was lower than the reference cement due to a delayed pozzolanic reaction. XRD analysis
of blended pastes revealed typical hydration phases like portlandite, C-S-H, Strätlingite, and
ettringite, with the ternary blends showing reduced portlandite content, indicating
absorption by the pozzolan's alumina phase. Durability assessments revealed that the
ternary blends exhibited improved resistance to water and chloride ion ingress. These
findings highlight the effectiveness of Nigerian calcined clays in producing durable and
sustainable concrete, supporting their use as supplementary cementitious materials to
reduce the environmental impact of concrete production.
the production of ternary blends of cement. Clay samples were obtained from three different
locations namely: Ikpeshi, Okpilla and Uzebba. The raw clay samples were then calcined at
700°C and 800°C. Chemical and mineralogical compositions were determined for the raw
and calcined clay samples using XRF and XRD respectively. The chemical composition
confirmed these clays as potential pozzolans with SiO2, Al2O3, and Fe2O3 collectively
exceeding 70%. XRD analysis identified kaolinite and quartz as major mineral phases in the
raw clays, which transformed into metakaolin upon calcination. Compressive strength tests
on mortar samples prepared with 50% substitution of Portland cement with the calcined
clay and limestone, showed that Ikpeshi clay at 800°C had the best strength performance,
with a strength activity index of 0.92 at 28 days, demonstrating superior pozzolanic
potential. Strength development was more significant between 7 and 28 days, indicating the
pozzolanic reaction's contribution to long-term strength. However, the initial strength at 3
days was lower than the reference cement due to a delayed pozzolanic reaction. XRD analysis
of blended pastes revealed typical hydration phases like portlandite, C-S-H, Strätlingite, and
ettringite, with the ternary blends showing reduced portlandite content, indicating
absorption by the pozzolan's alumina phase. Durability assessments revealed that the
ternary blends exhibited improved resistance to water and chloride ion ingress. These
findings highlight the effectiveness of Nigerian calcined clays in producing durable and
sustainable concrete, supporting their use as supplementary cementitious materials to
reduce the environmental impact of concrete production.
Keywords
Calcined clay
limestone
Nigerian clays.
Portland cement
Supplementary cementitious materials