Abstract
The present study includes preparation of high temperature superconductorBi2Sr2Ca2Cu3O10+and Bi2Ba2Ca2Cu3O10+by solid state reaction (SSR) method. The prepared samples were calcinaed at 800oC for 20 hours ,then regrind and pressed at pressure (0.7 GPa) into pellets, then sintered at 860oC for sintering times (140,160,180 and 200) hr.X-ray diffraction was used to determine the phases ,lattice constants (a,b&c ) and density of orthorhombic systems.Then study effect of sintering time on both two compounds and compare between them ,the highest Tcrecorded with sample (C) (Tc=103 K) for the compound Bi2Sr2Ca2Cu3O10+at sintering time (ts=180 hr) ; and (Tc=96 K ) sample (L) for the compound Bi2Ba2Ca2Cu3O10+at (ts=200 hr) it is the highest Tcrecorded.Also the study appeared prefer ability the first compoundBi2Sr2Ca2Cu3O10+on the other Bi2Ba2Ca2Cu3O10+because it records the highest Tcfor same sintering times ,creasing number of peaks of HTS(2223),up rise intensity and drop value resistively for this search.